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Journal articles
Polymeric nanofibers and nanofiber webs: a new class of nonwovens, International Nonwovens Journal, April 2003, Vol. 12(1) (581KB)

Polymeric nanofibers and nanofiber webs: a new class of nonwovens, International Nonwovens Journal, April 2003, Vol. 12(1) (581KB)

Journal articles
Open Access
Calculation of single chain cellulose elasticity using fully atomistic modeling, TAPPI JOURNAL April 2011

Calculation of single chain cellulose elasticity using fully atomistic modeling, TAPPI JOURNAL April 2011

Journal articles
TAPPI JOURNAL Summaries, Paper360° July/August 2011

TAPPI JOURNAL Summaries, Paper360º July/August 2011

Journal articles
Open Access
Preparation and characterization of bioactive and breathable

Preparation and characterization of bioactive and breathable polyvinyl alcohol nanowebs using a combinational approach, October 2016 TAPPI JOURNAL

Journal articles
Magazine articles
Open Access
Rice straw-based sustainable food packaging material with improved strength and barrier properties: Development and characterization, TAPPI Journal October 2023

ABSTRACT: Sustainable food packaging paper with high barrier and strength properties was developed with rice straw nanocellulose materials. Pulping and bleaching of rice straw were performed using an organosolv pulping and DED (D: chlorine dioxide bleaching; E: sodium hydroxide extraction) bleaching sequence. Bleached rice straw pulp was refined to 90°SR using a laboratory Valley beater. The laboratory handsheets were prepared using pulp slurry at 40°SR and 90°SR. The handsheets of cellulose nanofibrils (CNFs) made of highly refined pulp (90°SR) were surface sized using alkyl ketene dimer (AKD) wax to increase the barrier properties of paper for selective food packaging applications. The paper samples were tested for mechanical, optical, surface, and barrier properties, including tensile index, burst index, tearing index, bending stiffness, elongation, porosity, apparent density, opacity, Cobb value, water vapor transmission rate (WVTR), oil and grease resistance, and contact angle. The refined pulp (90°SR) was analyzed using field-emission scanning electron microscopy (FE-SEM), and it was observed that the morphology of the developed fibers changes to the nanoscale (<100 nm) for at least one dimension. The particle size distribution of the refined pulp using DLS analyzer also confirmed the cellulose fibers to near nanoscale. It was concluded that nanofibers were formed by a high degree of the mechanical pulp refining process and found to be much more economical than alternative processes in this direction. The sample handsheets of CNFs showed good strength and barrier properties. The barrier properties further increased when surface sizing was done using low-cost, nontoxic, and biodegradable AKD wax.

Journal articles
Magazine articles
Characterizing rheological behavior and fluidization of highly refined furnishes, TAPPI Journal April 2024

ABSTRACT: In this work, highly refined softwood bleached kraft pulp (SWBKP) furnishes, referred to here as XFC, were studied from the perspective of fiber suspension handling in processing. The rheology of the furnishes was studied with a rotational rheometer using a non-standard flow geometry to understand the viscosity development at different consistencies and the impact of temperature. For fluidization analysis during pipe flow, two optical methods were implemented; namely, optical coherence tomography (OCT) and high-speed video (HSV) imaging. The OCT was used to determine the small-scale floc structures near the pipe wall where the shear stress is highest, and the HSV imaging was applied for observing flow instabilities and XFC suspension uniformity at the pipe scale. All these issues can be significant in deciding the minimum flow rate required for a process pipe to get sufficient fluidization of XFC suspensions.

Journal articles
Magazine articles
Open Access
Rheological behavior of magnetic pulp fiber suspensions, TAPPI Journal June 2021

ABSTRACT: This paper is focused on the rheology of magnetic pulp suspensions in absence and presence of an external magnetic field. Magnetic fibers were prepared by the lumen loading method using bleached eucalyptus fibers and cobalt ferrite (CoFe2O4) nanoparticles. The effect of mass consistency, temperature, concentration of magnetic fibers, and magnetic field strength on yield stress and apparent viscosity of the suspensions were investigated. In the absence of an applied field, a dependence of yield stress with consistency, as well as with the percentage of magnetic fibers present in the suspension, was found. In flow tests, all the suspensions exhibited shear-thinning behavior, showing that the viscosity is only affected by the consistency of the suspension. On the other hand, magnetorheological measurements show a negative effect of the applied magnetic field on the viscosity of the suspension.

Journal articles
Magazine articles
Unlocking Product Potential with Renewable Nanomaterials, Paper360º March/April 2019

Unlocking Product Potential with Renewable Nanomaterials, Paper360º March/April 2019

Journal articles
Magazine articles
Open Access
Research needs for nanocellulose commercialization and applications

INTRODUCTION: This short review deals with some applications and research needs for nanocellulosic (NC) materials; primarily cellulose nanocrystals (CNC), cellulose nanofibers (CNF), and bacterial cellulose (BC). Whereas CNC and BC materials are fairly homogenous, CNF materials represent a wide sector of different materials, often with a high heterogeneity. This is due to different pretreatment methods (mechanical, chemical, enzymatic), woodbased or agricultural-based materials, delignification and bleaching procedures, etc. The purpose of this comprehensive review is not to discuss the various production methods, for which the reader may consult with a selected number of reviews [1-6]; thus, the focus is on practical applications. Practical applications and potential markets were also discussed some years ago by other investigators [7-8]. Upscaling and choice of pretreatment methods, as well as economic considerations and different business models, have also been discussed, along with: œ Toxicity and environmental issues [9-10] œ The complex characterization of cellulose nanomaterials [4] The reader should also be aware of new contenders to the three classic groups of cellulosic nanomaterials, which are already in a commercial phase. These include cellulose filaments [11-12] and materials from mechanical grinding processes [13], and these materials may be nanostructures or not, depending on our classification. Finally, as indicated by the editorial on p. 275, scientists are currently taking a deep dive into the fundamental features of nanocellulosic materials [14-15].

Journal articles
Magazine articles
TAPPI News, Paper360º May/June 2018

TAPPI News, Paper360º May/June 2018