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Rice straw-based sustainable food packaging material with improved strength and barrier properties: Development and characterization, TAPPI Journal October 2023
ABSTRACT: Sustainable food packaging paper with high barrier and strength properties was developed with rice straw nanocellulose materials. Pulping and bleaching of rice straw were performed using an organosolv pulping and DED (D: chlorine dioxide bleaching; E: sodium hydroxide extraction) bleaching sequence. Bleached rice straw pulp was refined to 90°SR using a laboratory Valley beater. The laboratory handsheets were prepared using pulp slurry at 40°SR and 90°SR. The handsheets of cellulose nanofibrils (CNFs) made of highly refined pulp (90°SR) were surface sized using alkyl ketene dimer (AKD) wax to increase the barrier properties of paper for selective food packaging applications. The paper samples were tested for mechanical, optical, surface, and barrier properties, including tensile index, burst index, tearing index, bending stiffness, elongation, porosity, apparent density, opacity, Cobb value, water vapor transmission rate (WVTR), oil and grease resistance, and contact angle. The refined pulp (90°SR) was analyzed using field-emission scanning electron microscopy (FE-SEM), and it was observed that the morphology of the developed fibers changes to the nanoscale (<100 nm) for at least one dimension. The particle size distribution of the refined pulp using DLS analyzer also confirmed the cellulose fibers to near nanoscale. It was concluded that nanofibers were formed by a high degree of the mechanical pulp refining process and found to be much more economical than alternative processes in this direction. The sample handsheets of CNFs showed good strength and barrier properties. The barrier properties further increased when surface sizing was done using low-cost, nontoxic, and biodegradable AKD wax.
Journal articles
Magazine articles
Paper coated with sonochemically synthesized zinc oxide nanoparticles: Enhancement of properties for preservation of documents, TAPPI JOURNAL January 2017
Paper coated with sonochemically synthesized zinc oxide nanoparticles: Enhancement of properties for preservation of documents, TAPPI JOURNAL January 2017
Journal articles
Magazine articles
Nanocellulose in Japan: An industrial perspective, TAPPI Journal April 2019
ABSTRACT: With the maturing of Japan’s economy, domestic demand for paper and paperboard is more likely to level off in the long term. Japanese paper companies are accelerating overseas production, especially in the emerging Asian markets, while strengthening competitiveness of domestic mills and developing new products. In Japan, we have always focused on emerging technologies and driving innovation in the pulp and paper industry. As a business definition, innovation does not equal innovative technology. Innovative technology can become innovation only when it is commercialized and used in industry.
Journal articles
Editor's Note: Nanotechnology in the news, TAPPI JOURNAL July 2010
Editor's Note: Nanotechnology in the news, TAPPI JOURNAL July 2010
Journal articles
Magazine articles
Investigation on the recycling of sulfuric acid from pretreatment of cellulose for nanocellulose preparation, TAPPI JOURNAL February 2020
ABSTRACT: Sulfuric acid is often used to pretreat cellulose prior to homogenization and conversion to nanocellulose. It would be economically significant to reuse the acid to close the overall value chain loop. The target of this work was to investigate the effect of recovery and recycling frequency of sulfuric acid from the pretreatments on the pretreatment yield of water-insoluble cellulose solid residue, and to explore the relationship between the nanocellulose size prepared by recovery of acid and number of cycles. The surface properties of the nanocelluloses were measured, including content of sulfate groups, absolute zeta potential, crystallinity, and thermal stability.
Journal articles
Nanocellulose in polymer composites and biomedical applications
Nanocellulose in polymer composites and biomedical applications, TAPPI JOURNAL June 2014
Journal articles
Thermal gravimetric analysis of in-situ crosslinked nanocellulose whiskers â?¢ poly(methyl vinyl ether-co-maleic acid) â?¢ polyethylene glycol, TAPPI JOURNAL April 2011
Thermal gravimetric analysis of in-situ crosslinked nanocellulose whiskers • poly(methyl vinyl ether-co-maleic acid) • polyethylene glycol, TAPPI JOURNAL April 2011
Journal articles
Nanolayer polymeric optical films, TAPPI JOURNAL, June 1992, Vol. 75(6)
Nanolayer polymeric optical films, TAPPI JOURNAL, June 1992, Vol. 75(6)
Journal articles
Nanoscale morphology of lignins and their chemical transformation products, TAPPI JOURNAL, March 1996, Vol. 79(3)
Nanoscale morphology of lignins and their chemical transformation products, TAPPI JOURNAL, March 1996, Vol. 79(3)
Journal articles
Magazine articles
The winding mechanics of laminate webs, TAPPI Journal February 2020
ABSTRACT: Models that describe the residual stresses due to winding single-layer webs at the end of roll-to-roll manufacturing machines are mature. These models have been used to reduce or avoid defects that are due to winding. Many laminated products exist where two or more webs have been joined to form a thicker composite web. The properties of the web layers provide a unique functionality to the product being manufactured. No laminate winding models exist in the literature. This paper will focus on the development of a laminate winding model and laboratory test verification of the model.
