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Journal articles
Open Access
Techniques for expanding the sphere of statistical process control, TAPPI JOURNAL July 1988

Techniques for expanding the sphere of statistical process control, TAPPI JOURNAL July 1988

Journal articles
Open Access
Fibers properties and tearing resistance, TAPPI JOURNAL February 1988 88FEB103

Fibers properties and tearing resistance, TAPPI JOURNAL February 1988

Journal articles
Magazine articles
Open Access
Probing the molecular weights of sweetgum and pine kraft lignin fractions, TAPPI Journal June 2021

ABSTRACT: The present investigation undertook a systematic investigation of the molecular weight (MW) of kraft lignins throughout the pulping process to establish a correlation between MW and lignin recovery at different extents of the kraft pulping process. The evaluation of MW is crucial for lignin characterization and utilization, since it is known to influence the kinetics of lignin reactivity and its resultant physico-chemical properties. Sweetgum and pine lignins precipitated from black liquor at different pHs (9.5 and 2.5) and different extents of kraft pulping (30•150 min) were the subject of this effort. Gel permeation chromatography (GPC) was used to determine the number average molecular weight (Mn), mass average molecular weight (Mw), and polydispersity of the lignin samples. It was shown that the MW of lignins from both feedstocks follow gel degradation theory; that is, at the onset of the kraft pulping process low molecular weight-lignins were obtained, and as pulping progressed, the molecular weight peaked and subsequently decreased. An important finding was that acetobromination was shown to be a more effective derivatization technique for carbohydrates containing lignins than acetylation, the technique typically used for derivatization of lignin.

Magazine articles
Open Access
Views from the top: ceos offer global perspectives on the pulp and paper industries, TAPPI JOURNAL, August 1999, Vol. 82(8)

Views from the top: ceos offer global perspectives on the pulp and paper industries, TAPPI JOURNAL, August 1999, Vol. 82(8)

Journal articles
Magazine articles
Open Access
Kraft pulp viscosity as a predictor of paper strength: Its uses and abuses, TAPPI Journal October 2023

ABSTRACT: For bleached kraft pulps, two factors govern paper strength: the individual fiber strength, and the bond strength that adheres the individual fibers together in the paper matrix. Inherent fiber strength is related to the length of the carbohydrate polymers, also known as the degree of polymerization (DP). Average DP (DP) is inferred by performing pulp viscosity measurements. Under certain circumstances during kraft pulping and bleaching, the average polymer lengths can be shortened, resulting in lower pulp viscosity, and may indicate fiber damage. Fiber damage typically manifests itself as a reduction in tear strength for well-bonded handsheets.This paper will review the literature on how pulp viscosity can predict paper/fiber strength and how it can be used as a diagnostic tool. It can be a means to monitor pulp quality during pulping and bleaching, as well as to alert when such operations approach a critical threshold. However, viscosity losses must be carefully and judiciously analyzed. Like most diagnostic tools, viscosity measurements can be misused and abused, which can lead to incorrect inferences about intrinsic fiber strength. This review will also cover these misuses. The overall goal is to provide the papermaker a better understanding of what pulp viscosity is, how it correlates to potential sheet strength, and what its limitations are. It will be illustrated that when pulp viscosity drops below a critical value, it will indicate an appreciable deterioration in the paper’s tear and tensile strength.

Journal articles
Magazine articles
Open Access
The role of hornification in the deterioration mechanism of physical properties of unrefined eucalyptus fibers during paper recycling, TAPPI Journal February 2024

ABSTRACT: Physical properties of cellulosic paper deteriorate significantly during paper recycling, which hinders the sustainable development of the paper industry. This work investigates the property deterioration mechanism and the role of hornification in the recycling process of unrefined eucalyptus fibers. The results showed that during the recycling process, the hornification gradually deepened, the fiber width gradually decreased, and the physical properties of the paper also gradually decreased. After five cycles of reuse, the relative bonding area decreased by 17.6%, while the relative bonding force decreased by 1.8%. Further results indicated that the physical property deterioration of the paper was closely related to the decrease of fiber bonding area. The fiber bonding area decreased linearly with the reduction of re-swollen fiber width during paper recycling. Re-swollen fiber width was closely related to the hornification. Hornification mainly reduces the bonding area of unrefined eucalyptus fiber rather than the bonding force. The work elucidates the role of hornification in the recycling process of unrefined eucalyptus fibers and the deterioration mechanism of paper physical properties, which will be helpful to control the property deterioration of paper and achieve a longer life cycle.

Journal articles
Magazine articles
Open Access
Ultrastructural Behavior of Cell Wall Polysaxxharides, TAPPI Journal April 2022

ABSTRACT: Considerable information on the ultrastructural organization of the plant cell wall and the supermolecular arragement of the cell wall components, in particular of cellulose, has been obtained with the electron microscope.

Journal articles
Open Access
Conference review: Recycling sessions at TAPPI PEERS, TAPPI JOURNAL February 2012

Conference review: Recycling sessions at TAPPI PEERS, TAPPI JOURNAL February 2012

Journal articles
Open Access
Canadian industry: 1996 review, TAPPI JOURNAL, January 1997, Vol. 80(1)

Canadian industry: 1996 review, TAPPI JOURNAL, January 1997, Vol. 80(1)

Journal articles
Open Access
Outsourcing providers, TAPPI JOURNAL, February 1997, Vol. 80(2)

Outsourcing providers, TAPPI JOURNAL, February 1997, Vol. 80(2)